KML/KMZ files and layers can be a little complex at times and most people have issues at times. Here are some recommendations and suggestions that should come in handy:-

 

<LineStyle>

    <color>ff0000ff</color>

</LineStyle>
<LineStyle>

    <color>ff0000ff</color>

    <width>1</width>

</LineStyle>


You can find the KML reference guide here:http://code.google.com/apis/kml/documentation/kmlreference.html