KML/KMZ files and layers can be a little complex at times and most people have issues at times. Here are some recommendations and suggestions that should come in handy:-
<LineStyle> <color>ff0000ff</color> </LineStyle> |
<LineStyle> <color>ff0000ff</color> <width>1</width> </LineStyle> |
You can find the KML reference guide here:http://code.google.com/apis/kml/documentation/kmlreference.html